Cycloaurated triphenylphosphine-sulfide and –selenide

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Title

Cycloaurated triphenylphosphine-sulfide and –selenide

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University of Waikato

Collection

ResearchCommons@Waikato

Description

The first examples of cycloaurated phosphine sulfides and triphenylphosphine selenide have been synthesised; these complexes are fairly rare examples of gold(III) complexes with potentially reducing sulfur- and selenium-donor ligands. The cycloaurated complex (AuCl₂ (2-C₆H₄P(S)Ph₂) was synthesised in good yield by transmetallation of the organomercury precursor Hg(2-C₆H₄P(S)Ph₂)₂ with Me₄N[AuCl₄]. A route to the chloro-mercury analogue ClHg(2-C₆H₄P(S)Ph₂) was developed by reaction of the cycl...

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Format

Research Paper

Research format

Journal article

Date created

2010

Creator

Kilpin, Kelly Joan / Henderson, William / Nicholson, Brian K.

URL

https://hdl.handle.net/10289/3640

Related subjects

gold complexes / cyclometallated ligands / phosphine chalcogenides / X-ray crystal structure / organomercury compounds

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