Synthesis of diisopropylcyclopropenone and X-ray structure of its dichlorodimethyltin(IV) adduct

About this item

Title

Synthesis of diisopropylcyclopropenone and X-ray structure of its dichlorodimethyltin(IV) adduct

Content partner

University of Canterbury Library

Collection

UC Research Repository

Description

Diisopropylcyclopropenone was prepared by a dehydrobromination of 3,5-dibromo-2,6-dimethylheptan-4-one and isolated in 18% yield via an aqueous extraction procedure. It was characterised by an X-ray crystal structure analysis of its complex with dichlorodimethyltin(IV): Dichlorodimethyl(diisopropylcyclopropenone)tin(IV) was found to have a chloro-bridged dimeric structure in the solid state.

Format

Research paper

Research format

Journal article

Date created

2006

Creator

Curnow, O.J. / Fern, G.M. / Pipal, R.J.

URL

http://hdl.handle.net/10092/603

Related subjects

crystal structure / cyclopropenone / tin complex / Fields of Research::250000 Chemical Sciences::250300 Organic Chemistry::250399 Organic chemistry not elsewhere classified / Fields of Research::250000 Chemical Sciences::250100 Physical Chemistry (Incl. Structural)::250105 Structural chemistry

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