Research paper

Synthesis of benzannulated spiroketals using an oxidative radical cyclization

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Title
Synthesis of benzannulated spiroketals using an oxidative radical cyclization
Content partner
The University of Auckland Library
Collection
ResearchSpace@Auckland
Description

The synthesis of both mono and bisbenzannulated spiroketals using an oxidative radical cyclization approach is investigated. Although unsuccessful in uncovering a novel route toward bisbenzannulated spiroketals, the oxidative radical cyclization does facilitate a new approach to monobenzannulated spiroketals such as those found in berkelic acid and in the chaetoquadrins.

Format
Research paper
Research format
Journal article
Date created
2011
Creator
Sperry, Jonathan / Liu, YC / Wilson, Zoe / Hubert, JG / Brimble, Margaret
URL
http://hdl.handle.net/2292/8441
Related subjects
spiroketals / berkelic acid / chaetoquadrin / radical cyclization / cross-metathesis / INTRAMOLECULAR HYDROGEN ABSTRACTION / BERKELIC ACID / CROSS-METATHESIS / NATURAL-PRODUCTS / GAMMA-RUBROMYCIN / (-)-BERKELIC ACID / CONVERGENT ROUTE / HUMAN TELOMERASE / FORMAL SYNTHESIS / DNA HELICASE

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