Cycloaurated gold(III) complexes with monoanionic thiourea ligands

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Title

Cycloaurated gold(III) complexes with monoanionic thiourea ligands

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University of Waikato

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ResearchCommons@Waikato

Description

Using a simple one-pot procedure, reaction of cycloaurated gold(III) dihalide complexes [LAuCl₂] (L = 2-benzylpyridyl, 2-anilinopyridyl) with trisubstituted thioureas PhNHC(S)NR₂ (R = Me, Cy) and Me3N in methanol, followed by addition of excess NaBPh₄ gave the salts [Lau{SC(-NR₂)NPh}]⁺BPH₄⁻ containing N,S-chelated thiourea monoanion ligands. The compounds were obtained in good yields, and were characterised by ESI MS, elemental microanalysis and in two cases by X-ray structure determinations....

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Format

Research Paper

Research format

Journal article

Date created

2013-11

Creator

Smith, Tiffany Sharee / Henderson, William / Nicholson, Brian K.

URL

https://hdl.handle.net/10289/8343

Related subjects

gold complexes / thiourea ligand / cycloaurated complexes / crystal structure / electrospray ionisation mass spectrometry

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