Synthesis, Properties, and Coordination Chemistry of t-Bu-Xantphos Ligands

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Title

Synthesis, Properties, and Coordination Chemistry of t-Bu-Xantphos Ligands

Content partner

Victoria University of Wellington

Collection

Open Access Victoria University of Wellington

Description

This thesis provides an account of research into a group of diphosphine ligands with a rigid xanthene backbone and tert -butyl substituents on the phosphorus atoms. The three ligands have different groups in the bridgehead position of the backbone (CMe₂, SiMe₂, or S) which change the natural (calculated) bite-angle of the ligand. The coordination chemistry of these t -Bu-xantphos ligands with late-transition metals has been investigated with a focus on metal complexes that may form in catalyt...

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Format

Research paper

Research format

Scholarly text / Thesis

Thesis level

Doctoral

Date created

2021

Creator

Nelson, Melanie Ruth Maria

URL

https://figshare.com/articles/thesis/Synthesis_Properties_and_Coordination_Chemistry_of_t-Bu-Xant...

Related subjects

Transition metal chemistry / Xantphos / Diphosphine Ligands / Late Transition Metals / School: School of Chemical and Physical Sciences / Transition Metal Chemistry / Degree Discipline: Chemistry / Degree Level: Doctoral / Degree Name: Doctor of Philosophy

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