Enantioselective Total Synthesis of (R,R)-Blumenol B and d9-(R,R)-Blumenol B

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Title

Enantioselective Total Synthesis of (R,R)-Blumenol B and d9-(R,R)-Blumenol B

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The University of Auckland Library

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ResearchSpace@Auckland

Description

C13-norisoprenoids are of particular importance to grapes and wines, as these molecules influence wine aroma and have been shown to significantly contribute to the distinct character of various wine varieties. Blumenol B is a putative precursor to a number of important wine aroma compounds, including the well-known compounds theaspirone and vitispirane. The enantioselective synthesis of (R,R)-blumenol B from commercially available 4-oxoisophorone was achieved using a short and easily scaleabl...

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Format

Research paper

Research format

Journal article

Creator

Tan, Shi Min / Rees, Shaun WP / Jelley, Rebecca E / Wang, Jin / Fedrizzi, Bruno / Barker, David

URL

https://hdl.handle.net/2292/61927

Related subjects

0304 Medicinal and Biomolecular Chemistry / 0305 Organic Chemistry / 0307 Theoretical and Computational Chemistry

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