Synthetic Strategy Towards Heterodimetallic Half-Sandwich Complexes Based on a Symmetric Ditopic Ligand

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Title

Synthetic Strategy Towards Heterodimetallic Half-Sandwich Complexes Based on a Symmetric Ditopic Ligand

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The University of Auckland Library

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ResearchSpace@Auckland

Description

Multimetallic complexes have been shown in several examples to possess greater anticancer activity than their monometallic counterparts. The increased activity has been attributed to altered modes of action. We herein report the synthesis of a series of heterodimetallic compounds based on a ditopic ligand featuring 2-pyridylimine chelating motifs and organometallic half-sandwich moieties. The complexes were characterized by a combination of 1H NMR spectroscopy, electrospray ionization mass sp...

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Format

Research paper

Research format

Journal article

Creator

Green, Lewis PM / Steel, Tasha R / Riisom, Mie / Hanif, Muhammad / Söhnel, Tilo / Jamieson, Stephen MF / Wright, L James / Crowley, James D / Hartinger, Christian G

URL

https://hdl.handle.net/2292/68648

Related subjects

anticancer activity / bioorganometallics / heterodimetallic complexes / ligand exchange reactions / structural characterization / 3402 Inorganic Chemistry / 34 Chemical Sciences / Science & Technology / Physical Sciences / Chemistry, Multidisciplinary / Chemistry / RUTHENIUM COMPLEXES / PLATINUM COMPLEXES / ANTICANCER / IRIDIUM / BINDING / RHODIUM / DRUGS

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